Quick reference — Organic nomenclature

  • Alkanes: CₙH₂ₙ₊₂, suffix -ane.
  • Alkenes: CₙH₂ₙ, suffix -ene.
  • Alkynes: CₙH₂ₙ₋₂, suffix -yne.
  • Cycles: prefix "cyclo-" + parent name (cycloalkanes CₙH₂ₙ).
  • Substituents: methyl, ethyl, propyl; number the parent chain.
  • Isomerism: structural and stereoisomerism (R/S, Z/E or cis/trans).

Functional groups table

GroupStructureExample SMILES
Alcohol
Alcohol
Alcohol
CO
Aldehyde
Aldehyde
Aldehyde
CC=O
Ketone
Ketone
Ketone
CC(=O)C
Carboxylic acid
Carboxylic acid
Carboxylic acid
CC(=O)O
Ether
Ether
Ether
CCOCC
Amine
Amine
Amine
CCN

1. Write the molecular formula of ethane. (1 points)

2. Select the connectivity (structure) of 2-methylpropane. (1 points)

3. What type of isomerism does CH3-CH=CH-CH3 exhibit? (1 points)

4. Indicate the configuration (R or S) of the chiral center in CH3-CH(Br)(Cl)-H. (1 points)

5. What is the general formula for alkynes? (1 points)

6. Which functional group is present in HO-CH2-CH2-OH? (1 points)

7. What is the general formula for cycloalkanes? (1 points)

8. What is the name of the substituent CH3-? (1 points)