PropertyIonic Bond ⚡Covalent Bond 🔗Metallic Bond 🧲
Elements involvedMetal + NonmetalNonmetal + NonmetalMetals only
Electron behaviorTransferred (lost/gained)SharedDelocalized (“sea” of e⁻)
StructureCrystal latticeMolecules or networksMetal lattice
Melting pointHighLow–medium (very high in networks)Usually high
Electrical conductivityHigh when molten or dissolvedPoorHigh (solid state)
Solubility in waterOften solubleUsually lowInsoluble
Physical stateSolid (at room temp)Solid/liquid/gasSolid (except Hg)
ExamplesNaCl, MgOH₂O, CO₂, CH₄Fe, Cu, Al

Chemical Bonding

Chemical bonding is the force that holds atoms together in compounds, creating the incredible diversity of materials around us. From the salt in our food to the water we drink, from the metals in our buildings to the DNA in our cells, everything depends on how atoms bond together.

Ionic Bonding

Formed between metals and non-metals through electron transfer, creating charged ions that attract each other. Metals lose electrons to become positively charged cations, while non-metals gain electrons to become negatively charged anions.

Physical Properties

  • Crystal structure: Regular, repeating arrangement of ions
  • High melting/boiling points: Strong electrostatic attractions
  • Brittle: Shifting layers brings like charges together, causing repulsion
  • Hard: Strong ionic bonds resist deformation

Electrical Properties

  • Insulators when solid: Ions are fixed in the lattice
  • Conduct when molten: Ions are free to move
  • Conduct when dissolved: Ions dissociate in solution
  • Electrolytes: Aqueous solutions conduct electricity

Solubility

  • Polar solvents: Often soluble in water
  • Hydration: Water molecules surround and stabilize ions
  • Non-polar solvents: Usually insoluble
  • Lattice energy: Influences solubility

Covalent Bonding

Formed between non-metals through electron sharing. Atoms share pairs of electrons to achieve a stable electron configuration (often following the octet rule), forming molecules.

Physical Properties

  • Low to moderate melting/boiling points: Weak intermolecular forces (except network solids)
  • States: Can be gases, liquids, or soft solids
  • Not brittle: Many are flexible or soft
  • Exceptions: Giant covalent structures (e.g., diamond) are very hard

Electrical Properties

  • Poor conductors: No free charged particles
  • Exceptions: Graphite conducts due to delocalized electrons

Solubility

  • Polar molecules: May dissolve in water
  • Non-polar molecules: Dissolve in non-polar solvents
  • "Like dissolves like": Solubility depends on polarity

Types of Bonds

  • Single bond: One shared pair of electrons
  • Double bond: Two shared pairs of electrons
  • Triple bond: Three shared pairs of electrons

Metallic Bonding

Formed between metal atoms, where valence electrons become delocalized, creating a "sea of electrons" surrounding positively charged metal ions.

Properties from Metallic Bonding

Electrical Conductivity
  • Mobile electrons: Carry electric current
  • Excellent conductors: e.g., silver, copper, gold
  • Temperature effect: Conductivity decreases with increasing temperature
  • Non-directional: Conduct in all directions
Thermal Conductivity
  • Heat transfer: Mobile electrons carry thermal energy
  • Good thermal conductors: Same metals as electrical conductors
  • Applications: Heat sinks, cookware
Mechanical Properties
  • Malleability: Can be hammered into sheets
  • Ductility: Can be drawn into wires
  • Mechanism: Layers slide without breaking bonds
  • Non-directional bonding: Allows plastic deformation
Optical Properties
  • Metallic luster: Shiny appearance
  • Light interaction: Electrons absorb and re-emit light
  • Reflectivity: Good reflectors
  • Opacity: Do not transmit light

Key Improvements Made

  • Fixed typo: “The y create…” → removed and corrected section
  • Standardized capitalization (metals, non-metals)
  • Completed missing sections for covalent bonding
  • Ensured parallel structure across all bonding types
  • Improved scientific precision without overcomplicating
  • Removed redundancy and tightened phrasing
Intermolecular forces
In addition to primary chemical bonds, there are weaker forces that act between molecules, known as intermolecular forces. These forces influence the physical properties of substances, such as boiling and melting points, solubility, and viscosity.

They are responsible for properties such as the behavior of water, the ability of some substances to dissolve in others, and the states of matter (gases, liquids, and solids).

Since water (H₂O) is a polar molecule, it can form hydrogen bonds, which are a strong type of dipole–dipole interaction. This gives water its unique properties, such as high surface tension and a relatively high boiling point.

Similarly, molecules like NH₃ can also form hydrogen bonds. However, since ammonia is less polar than water, these interactions are weaker, resulting in lower boiling points and different physical properties.

Intermolecular forces also affect solubility. Polar substances tend to dissolve well in polar solvents (like water), while nonpolar substances dissolve better in nonpolar solvents (like oil). This is often summarized by the phrase "like dissolves like."

1. What are the three main types of chemical bonding? (Select all that apply) (1 points)

2. What determines the type of bond formed between two atoms? (1 points)

3. What happens to electrons in ionic bonding? (1 points)

4. What is the electron configuration that atoms try to achieve when bonding? (1 points)

5. Which type of bonding occurs between two non-metals? (1 points)

6. Chemical bonding concepts: (14 points)

a ) What is the maximum number of electrons in the outermost shell for stability (octet rule)?

b ) Which noble gas configuration does sodium achieve when it loses one electron?

c ) What type of bond forms between sodium and chlorine?

d ) How many electrons do two hydrogen atoms share in H₂?

e ) What is the name for a covalent bond where electrons are shared unequally?

f ) What type of bonding holds metal atoms together?

g ) What is the shape of a water molecule?

h ) What weak attraction exists between water molecules?

i ) What is the electronegativity difference range for ionic bonds?

j ) What type of crystal structure do ionic compounds typically form?

k ) What happens to the size of a metal atom when it forms a positive ion?

l ) What model describes metallic bonding as electrons moving freely?

m ) What force holds together molecules in molecular compounds?

n ) What is the bond angle in methane (CH₄)?

7. Why do atoms form chemical bonds? (1 points)

8. Which properties are typical of ionic compounds? (Select all that apply) (1 points)

9. What type of covalent bond has equal sharing of electrons? (1 points)

10. Which molecule has a linear molecular geometry? (1 points)

11. Which factors affect bond strength? (Select all that apply) (1 points)

12. What is a coordinate covalent bond? (1 points)

13. What determines molecular geometry according to VSEPR theory? (1 points)

14. Why are metals good conductors of electricity? (1 points)